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ChemicalBook >> CAS DataBase List >>4-Chlorophenylboronic acid

4-Chlorophenylboronic acid

CAS No.
1679-18-1
Chemical Name:
4-Chlorophenylboronic acid
Synonyms
AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid;4-CHLOROPHENYLBORNIC ACID
CBNumber:
CB0307561
Molecular Formula:
C6H6BClO2
Formula Weight:
156.37
MOL File:
1679-18-1.mol
MSDS File:
SDS

4-Chlorophenylboronic acid Properties

Melting point
284-289 °C(lit.)
Boiling point
295.4±42.0 °C(Predicted)
Density
1.32±0.1 g/cm3(Predicted)
storage temp.
Keep in dark place,Sealed in dry,Room Temperature
pka
8.39±0.10(Predicted)
form
Crystalline Powder
color
Off-white to beige
Water Solubility
2.5 g/100 mL
BRN
2936346
InChIKey
CAYQIZIAYYNFCS-UHFFFAOYSA-N
CAS DataBase Reference
1679-18-1(CAS DataBase Reference)
EWG's Food Scores

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H302-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P301+P312+P330
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38
Safety Statements  36-37/39-26
WGK Germany  3
RTECS  CY8950000
Hazard Note  Irritant
TSCA  No
HazardClass  IRRITANT
HS Code  29319090

4-Chlorophenylboronic acid price More Price(50)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 417548 4-Chlorophenylboronic acid 95% 1679-18-1 1g $20.4 2021-12-16 Buy
Sigma-Aldrich 417548 4-Chlorophenylboronic acid 95% 1679-18-1 10g $109 2021-12-16 Buy
TCI Chemical C1473 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 1679-18-1 5g $47 2022-04-27 Buy
TCI Chemical C1473 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 1679-18-1 25g $136 2022-04-27 Buy
Alfa Aesar A15657 4-Chlorobenzeneboronic acid, 98+% 1679-18-1 1g $19.2 2022-04-27 Buy
Product number Packaging Price Buy
417548 1g $20.4 Buy
417548 10g $109 Buy
C1473 5g $47 Buy
C1473 25g $136 Buy
A15657 1g $19.2 Buy

4-Chlorophenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

off-white to beige crystalline powder

Uses

suzuki reaction

Uses

4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.

Uses

4-Chlorophenylboronic acid can be used as a reactant in:
  • Palladium-catalyzed direct arylation.
  • Cyclopalladation.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
  • Copper-mediated ligandless aerobic fluoroalkylation.
  • Pd-catalyzed arylative cyclization.
  • Ruthenium catalyzed direct arylation.
  • Ligand-free copper-catalyzed coupling reactions.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.

It can also be used to prepare:
  • Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
  • Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
  • Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

106-47-8
1679-18-1
Synthesis of 4-Chlorophenylboronic acid from 4-Chloroaniline
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View Lastest Price from 4-Chlorophenylboronic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-12-15 4-Chlorophenylboronic acid
1679-18-1
 US $18.00 / g 1KG 99% 5ton/Month Qiuxian Baitai New Material Co., LTD
2021-11-30 4-Chlorophenylboronic acid
1679-18-1
 US $171.80 / KG 1g 99% 10Tons Baoji Guokang Bio-Technology Co., Ltd.
2021-11-02 4-Chlorophenylboronic acid
1679-18-1
 US $299.00 / Kg/Bag 1KG 99 10T Baoji Guokang Healthchem co.,ltd
4-Chlorophenylboronic acid,97% 4-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97% 4-Chlorophenylboronic acid,4-Chlorobenzeneboronic acid p-chlorophenylboronic aci (4-chlorophenyl)boronic acid(SALTDATA: 0.7H2O) 4-Chlorophenylboronic acid, 97% 5GR NSC 25408 BORONIC ACID, (4-CHLOROPHENYL)-;P-CHLOROBENZENEBORONIC ACID; p-chloro-benzeneboronicaci   (p-chlorophenyl)metaboric acid 4-Chlorophenylboronicacid,min.97% 4-CHLOROBENZENEBORONIC ACID / 4-CHLOROPHENYLBORONIC ACID PARACHLOROPHENYLBORONIC ACID 4-Chlorophenylboronic acid ,98% 4-Chlorophenylboronic acid, min. 97% (4-Chlorophenyl)boranic acid 4-Chlorophenylboranic acid 4-Chlorophenylboron dihydoxide 4-Chlorobenzeneboronic acid, 98+% 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) orobenzeneboronic Acid 4-Chlorophenylbronic Acid The effects of boric acid 4-Chlorophenylboronic acid 95% AC 34441 Benzeneboronic acid, p-chloro- WLN: QBQR DG B-(4-Chlorophenyl)boronic acid BORONIC ACID, (4-CHLOROPHENYL)- AKOS BRN-0011 4-CHLOROPHENYLBORNIC ACID 4-CHLOROPHENYLBORONIC ACID 4-CHLOROBENZENEBORONIC ACID P-CHLOROPHENYLBORONIC ACID P-CHLORO BENZENE BORONIC ACID RARECHEM AH PB 0178 boronicacid,p-chlorophenyl  4-Chlorophenylboronic acid,99% Boronic acid, B-(4-chlorophenyl)- 1679-18-1 1679-81-1 B (Classes of Boron Compounds) Boronic Acids Organometallic Reagents Boronic Acids and Derivatives Aryl blocks BoronicAcids Boronic Acid series Fluorin-contained phenyl boronic acid series Heterocyclic Compounds Boronic Acid Aryl Organoborons Boric acid Boronic acids Substituted Boronic Acids B (Classes of Boron Compounds)