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ChemicalBook >> CAS DataBase List >>D(+)-Phenylalaninol

D(+)-Phenylalaninol

CAS No.
5267-64-1
Chemical Name:
D(+)-Phenylalaninol
Synonyms
H-D-PHE-OL;H-D-Phen-ol;R-228060-001;D-PHENYLANINOL;D-PHEYLALANINOL;D-Penylalaninol;D-Phenylalanino;D-PHENYLALANINOL;PHENYLALANINOL-D;S/R-Phenylalaninol
CBNumber:
CB9741308
Molecular Formula:
C9H13NO
Formula Weight:
151.21
MOL File:
5267-64-1.mol
MSDS File:
SDS

D(+)-Phenylalaninol Properties

Melting point
93-95 °C(lit.)
alpha
23 º (c=1.2, 1 N HCl 22 ºC)
Boiling point
122 °C / 4mmHg
Density
1.0406 (rough estimate)
refractive index
23.5 ° (C=1.2, 1mol/L HCl)
storage temp.
Keep in dark place,Sealed in dry,Room Temperature
solubility
Soluble in Dichloromethane, Ethyl Acetate, Methanol.
pka
12.85±0.10(Predicted)
form
Crystalline Powder and Chunks
color
White to yellow
optical activity
[α]/D +22.8°, c = 1.2 in 1 M HCl
Sensitive
Air Sensitive
BRN
4665408
CAS DataBase Reference
5267-64-1(CAS DataBase Reference)
FDA UNII

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H318-H314
Precautionary statements  P280-P305+P351+P338-P310-P303+P361+P353
Hazard Codes  C,Xi
Risk Statements  34
Safety Statements  26-36/37/39-45-27
RIDADR  UN 3259 8/PG 3
WGK Germany  3
F  10-23
HazardClass  8
HazardClass  IRRITANT
PackingGroup  III
HS Code  29221990

D(+)-Phenylalaninol price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 284491 (R)-(+)-2-Amino-3-phenyl-1-propanol 98% 5267-64-1 1g $41.2 2021-12-16 Buy
Sigma-Aldrich 284491 (R)-(+)-2-Amino-3-phenyl-1-propanol 98% 5267-64-1 5g $86.3 2021-12-16 Buy
TCI Chemical P1289 D-Phenylalaninol >98.0%(GC)(T) 5267-64-1 5g $65 2022-04-27 Buy
TCI Chemical P1289 D-Phenylalaninol >98.0%(GC)(T) 5267-64-1 25g $198 2022-04-27 Buy
Alfa Aesar L09697 D-Phenylalaninol, 98% 5267-64-1 1g $39.6 2021-12-16 Buy
Product number Packaging Price Buy
284491 1g $41.2 Buy
284491 5g $86.3 Buy
P1289 5g $65 Buy
P1289 25g $198 Buy
L09697 1g $39.6 Buy

D(+)-Phenylalaninol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption.

Uses

D-Phenylalaninol is used as a chiral auxiliary for asymmetric Michael reactions. It is an enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.

Purification Methods

It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]

Global( 416)Suppliers
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371-66670886 info@dakenchem.com China 15392 58
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021-57951555 +8618017249410 jack.li@time-chemicals.com China 1807 55
+86-0371-55982848 sales@coreychem.com China 29960 58
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View Lastest Price from D(+)-Phenylalaninol manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2022-02-25 D(+)-Phenylalaninol
5267-64-1
 US $0.00 / KG 100g 98%+ 100kg WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD
2021-11-02 D(+)-Phenylalaninol
5267-64-1
 US $444.00 / Kg/Bag 1Kg/Bag 99% 10T Baoji Guokang Healthchem co.,ltd
2021-09-29 D(+)-Phenylalaninol
5267-64-1
 US $0.00 / Kg/Drum 1KG 98%min 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
D-(+)-Phenylalinol S/R-Phenylalaninol (2R)-2-amino-3-phenylpropan-1-ol BENZENEPROPANOL, .BETA.-AMINO-, (.BETA.R)- D-Penylalaninol D-PHEYLALANINOL D-PHENYLANINOL (D)-(+)-2-PHENYLALANINOL / D-(+)-2-AMINO-3-PHENYL-1-PROPANOL D-Phenylalaninol(R+Phenylalaninol) Benzenepropanol, beta-amino-, (R)- D-Phenylalaninol ,98% (R)-3-Phenyl-2-amino-1-propanol (R)-3-Phenyl-2-aminopropane-1-ol (αR)-α-(Hydroxymethyl)benzeneethanamine H-D-Phen-ol D(+)-2-Amino-3-phenyl-1-propanol,98% D-PHENYLALANINOL ((R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL) ((1R)-1-HydroxyMethyl-2-phenylethyl)aMine (2R)-2-AMino-3-phenyl-1-propanol (R)-(+)-2-AMino-3-phenyl-1-glycinol (R)-2-AMino-1-hydroxy-3-phenylpropane (R)-2-BenzylethanolaMine (βR)-β-AMino-benzenepropanol D-Phenylalaninol, (2R)-2-Amino-1-hydroxy-3-phenylpropane BENZENEPROPANOL, B-AMINO-, (BR)- D-(R)-PHENYLALANINOL (+)-D-PHENYLALANINOL D(+)-PHENYLALANINOL D-PHENYLALANINOL D-ALPHA-PHENYLALANINOL D(+)-2-AMINO-3-PHENYL-1-PROPANOL D-2-PHENYLALANINOL H-D-PHE-OL H-D-PHENYLALANINOL (R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL (R)-2-AMINO-3-PHENYL-1-PROPANOL (R)-2-AMINO-3-PHENYL-PROPAN-1-OL (R)-(+)-PHENYLALANINOL (R)-PHENYLALANINOL PHENYLALANINOL-D (R)-2-amino-3-phenylpropanol (R)-2-Amino-3-phenyl-1-propanol D(+)-Phenylalaninol D(+)-2-Amino-3-phenyl-1-propanol D-2-Amino-3-phenyl-1-propanol,99%e.e. R-228060-001 (R)-(+)-2-Amino-3-phenyl-1-propanol 98% D-Phenylalaninol> Benzenepropanol, β-amino-, (βR)- D-Phenylalanino D(+)-Phenylalaninol USP/EP/BP D-(+)-2-Amino-3-phenyl-1-proanol (+)-D-Phenylalaninol 5267-64-1 15267-64-1 Amino Alcohols (Chiral) Chiral Building Blocks Asymmetric Synthesis Amino Acid Derivatives Amino Alcohols